SCHEDULED MAINTENANCE
The reaction of 17β-acetoxy-1α,2-epoxy-1-methyl-5α-androstan-3-one with formic acid gives an A-nor-2-oxo-steoid carrying a formyl group at the 1-position. The formyl group is removed in alkaline media. O.r.d. and n.m.r. measurements on the products allowed the assignment of stereochemistry at C-1.
V. Tortorella, L. Toscano, C. Vetuschi and A. Romeo, J. Chem. Soc. C, 1971, 2422 DOI: 10.1039/J39710002422
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