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Issue 0, 1971
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Reactions of tris(dimethylamino)stibine with organic compounds

Abstract

Tris(dimethylamino)stibine (I) reacts with aldehydes and ketones to give gem-diamines and enamines. The reaction with acetic anhydride gives NN-dimethylacetamide along with stibine oxide or tris(acetoxy)stibine. depending upon the conditions. Reactions of tris(dimethylamino)stibine (I) with carbon dioxide, phenyl isocyanate, and phenyl isothiocyanate afford the triscarbamato-, ureido-, and thioureido-derivative of stibine, as the result of insertion of the heterocumulenes across the antimony–nitrogen bonds in tris(dimethylamino)stibine.

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Article information


J. Chem. Soc. C, 1971, 511-513
Article type
Paper

Reactions of tris(dimethylamino)stibine with organic compounds

J. Koketsu and Y. Ishii, J. Chem. Soc. C, 1971, 511
DOI: 10.1039/J39710000511

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