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Issue 18, 1970
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Aryne chemistry. Part XXVII. The photolysis of 1,2-di-iodotetrafluorobenzene in the presence of benzene

Abstract

The photolysis of 1,2-di-iodotetrafluorobenzene in the presence of benzene and benzene–hexane mixtures gives products derived from the 2-iodotetrafluorophenyl radical and from tetrafluorobenzyne. The aryne product, 5,6,7,8-tetrafluoro-1,4-dihydro-1,4-ethenonaphthalene, is photoisomerised in part to tetrafluorobenzocyclooctene(2).

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Article type: Paper
DOI: 10.1039/J39700002569
J. Chem. Soc. C, 1970, 2569-2572

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    Aryne chemistry. Part XXVII. The photolysis of 1,2-di-iodotetrafluorobenzene in the presence of benzene

    J. P. N. Brewer, I. F. Eckhard, H. Heaney, M. G. Johnson, B. A. Marples and T. J. Ward, J. Chem. Soc. C, 1970, 2569
    DOI: 10.1039/J39700002569

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