SCHEDULED MAINTENANCE
Hydrolysis of p-nitroaniline in aqueous sodium hydroxide was found to be second order with an activation energy of 17 kcal./mole and an entropy of activation of ca.–33 e.u. Absence of a significant nitrogen isotope effect for the reaction established that C–N bond stretching was unimportant in the rate-determining transition state.
G. Ayrey and W. A. Wylie, J. Chem. Soc. B, 1970, 738 DOI: 10.1039/J29700000738
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...