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Chlorine-containing species have been formed on the surface of MgO and detected at 77 K by e.s.r. spectroscopy. The spectra have been examined in detail and the species have been tentatively identified as chlorine atoms. The g-factor and nuclear hyperfine interaction have been interpreted and are in agreement with a recent analysis for the isoelectronic S– ion.
A. J. Tench and J. F. J. Kibblewhite, J. Chem. Soc. A, 1971, 2282 DOI: 10.1039/J19710002282
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