Issue 0, 1968

The temperature-dependence of arrhenius parameters

Abstract

Published entropy data are used to evaluate the temperature-dependence of the ratio of Arrhenius A factors of a wide variety of equilibria involving alkyl radicals. The results are used to estimate minimum temperature-dependences of A factors of individual processes. It is suggested that their experimental determination is feasible for a number of types of reaction.

Article information

Article type
Paper

J. Chem. Soc. A, 1968, 2301-2304

The temperature-dependence of arrhenius parameters

R. M. Marshall and J. H. Purnell, J. Chem. Soc. A, 1968, 2301 DOI: 10.1039/J19680002301

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