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Issue 0, 1966
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Orbital splittings of some tetragonal nickel(II) complexes with heterocyclic amine ligands

Abstract

Electronic spectra (5000–20,000 cm.–1) are reported for some complexes of the types NiL4X2 and polymeric NiL2X2(where L = pyridine, isoquinoline, and 3- and 4-methylpyridine; X = Cl, Br, or I) at room temperature and, in some cases, at ca. 80°K. The bands due to the transitions 3A2g3T2g and 3A2g3T1g(F) in Oh symmetry are split. From the observed band splittings the relative d-orbital energies are deduced by use of electrostatic and molecular orbital models.

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Article type: Paper
DOI: 10.1039/J19660001769
J. Chem. Soc. A, 1966, 1769-1772

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    Orbital splittings of some tetragonal nickel(II) complexes with heterocyclic amine ligands

    D. M. L. Goodgame, M. Goodgame, M. A. Hitchman and M. J. Weeks, J. Chem. Soc. A, 1966, 1769
    DOI: 10.1039/J19660001769

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