Issue 20, 2019

Catalyst- and additive-free Baeyer–Villiger-type oxidation of α-iodocyclopentenones to α-pyrones: using air as the oxidant

Abstract

An efficient synthetic approach for the synthesis of α-pyrones via Baeyer–Villiger-type oxidation of α-iodocyclopentenones through a catalyst- and additive-free system using air as an environmentally benign oxidant is described. The reaction exhibits excellent functional group compatibility and provides a simple and efficient protocol for the construction of highly functionalized α-pyrones under mild reaction conditions.

Graphical abstract: Catalyst- and additive-free Baeyer–Villiger-type oxidation of α-iodocyclopentenones to α-pyrones: using air as the oxidant

Supplementary files

Article information

Article type
Paper
Submitted
03 Aug 2019
Accepted
09 Sep 2019
First published
10 Sep 2019

Green Chem., 2019,21, 5611-5615

Catalyst- and additive-free Baeyer–Villiger-type oxidation of α-iodocyclopentenones to α-pyrones: using air as the oxidant

Y. Zhou, X. Chen, X. Ling and W. Rao, Green Chem., 2019, 21, 5611 DOI: 10.1039/C9GC02725D

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