Application of the Cu(I)/TEMPO/O2 catalytic system for aerobic oxidative dehydrogenative aromatization of pyrrolidines

Zheng Luo; Yan Liu; Chao Wang; Danjun Fang; Junyu Zhou; Huayou Hu

doi:10.1039/C9GC01932D

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Application of the Cu(i)/TEMPO/O₂ catalytic system for aerobic oxidative dehydrogenative aromatization of pyrrolidines†

Zheng Luo,^ab Yan Liu,^ab Chao Wang,^a Danjun Fang,

^c Junyu Zhou^c and Huayou Hu

*^b

Author affiliations

* Corresponding authors

^a School of Material Science and Engineering, Southwest University of Science and Technology, Mianyang 621010, P. R. China

^b Jiangsu Key Laboratory for Chemistry of Low-Dimensional Materials, School of Chemistry and Chemical Engineering, Huaiyin Normal University, Huaian 223300, P. R. China
E-mail: HuayouHu@hytc.edu.cn

^c Department of Pharmacology, Nanjing Medical University, Nanjing, Jiangsu 210029, China

Abstract

A Cu(I)/TEMPO (2,2,6,6-tetramethyl-1-piperidinyloxy)-catalyzed aerobic oxidative dehydrogenative aromatization reaction of fully saturated pyrrolidines to synthesize multi-substituted pyrroles was developed for the first time. The use of a non-precious metal catalyst, green oxidant and environmentally friendly solvent made the reaction more sustainable.

Download options Please wait...

Associated articles

Correction: Application of the Cu(i)/TEMPO/O2 catalytic system for aerobic oxida…

Supplementary files

Supplementary information PDF (3212K)

Article information

DOI: https://doi.org/10.1039/C9GC01932D
Article type: Communication
Submitted: 11 Jun 2019
Accepted: 29 Jul 2019
First published: 29 Jul 2019

Download Citation

Green Chem., 2019,21, 4609-4613

Permissions

Request permissions

Application of the Cu(I)/TEMPO/O₂ catalytic system for aerobic oxidative dehydrogenative aromatization of pyrrolidines

Z. Luo, Y. Liu, C. Wang, D. Fang, J. Zhou and H. Hu, Green Chem., 2019, 21, 4609 DOI: 10.1039/C9GC01932D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Green Chemistry