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Issue 14, 2019
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Organic aluminum hydrides catalyze nitrile hydroboration

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Abstract

Economical and eco-friendly aluminum hydrides were shown to be highly efficient catalysts for the solvent-free hydroboration of various nitriles using pinacolborane. The catalytic activities of three organic aluminum hydrides were compared. Mechanism investigation experiments revealed that nitrile was reduced to an imine intermediate by aluminum hydrides.

Graphical abstract: Organic aluminum hydrides catalyze nitrile hydroboration

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Publication details

The article was received on 17 May 2019, accepted on 27 Jun 2019 and first published on 01 Jul 2019


Article type: Communication
DOI: 10.1039/C9GC01659G
Green Chem., 2019,21, 3812-3815

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    Organic aluminum hydrides catalyze nitrile hydroboration

    W. Liu, Y. Ding, D. Jin, Q. Shen, B. Yan, X. Ma and Z. Yang, Green Chem., 2019, 21, 3812
    DOI: 10.1039/C9GC01659G

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