Issue 9, 2016

[bmIm]OH-catalyzed amidation of azides and aldehydes: an efficient route to amides

Abstract

A [bmIm]OH-catalyzed amidation of azides and aldehydes is reported. This reaction is easily handled and proceeds under mild conditions. The overall transformation involves azide–enolate cycloaddition, which subsequently undergoes rearrangement to give amides. Importantly, the employment of ionic liquid makes this transformation green and practical.

Graphical abstract: [bmIm]OH-catalyzed amidation of azides and aldehydes: an efficient route to amides

Supplementary files

Article information

Article type
Communication
Submitted
11 Feb 2016
Accepted
15 Feb 2016
First published
26 Feb 2016

Green Chem., 2016,18, 2604-2608

[bmIm]OH-catalyzed amidation of azides and aldehydes: an efficient route to amides

L. Gu, W. Wang, J. Liu, G. Li and M. Yuan, Green Chem., 2016, 18, 2604 DOI: 10.1039/C6GC00402D

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