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Issue 4, 2016
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Transition-metal-free regioselective synthesis of alkylboronates from arylacetylenes and vinyl arenes

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Abstract

A transition-metal-free synthesis of alkylboronates, utilizing arylacetylenes or vinyl arenes and bis(pinacolato)diboron through tandem borylation and protodeboronation, has been developed. This reaction is efficient, practical and environmentally benign, leading to anti-Markovnikov products with excellent regioselectivity, broad functional group tolerance and excellent yields in both small and gram scales.

Graphical abstract: Transition-metal-free regioselective synthesis of alkylboronates from arylacetylenes and vinyl arenes

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Supplementary files

Article information


Submitted
03 Nov 2015
Accepted
22 Dec 2015
First published
06 Jan 2016

Green Chem., 2016,18, 932-936
Article type
Communication

Transition-metal-free regioselective synthesis of alkylboronates from arylacetylenes and vinyl arenes

K. Yang and Q. Song, Green Chem., 2016, 18, 932
DOI: 10.1039/C5GC02633D

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