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Issue 8, 2015
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The ionic liquid microphase enhances the catalytic activity of Pd nanoparticles supported by a metal–organic framework

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Abstract

Here we demonstrate the utilization of the ionic liquid (IL) microphase for enhancing the catalytic activities of the metal nanoparticles supported on a MOF. The IL microphase offers an excellent environment for stabilizing metal nanoparticles. A new heterogeneous catalyst Pd/IL/MOF is developed, which combines the advantages of highly dispersed small Pd nanoparticles, the IL microphase and a porous MOF. The as-synthesized Pd/IL/MOF catalysts have shown high catalytic activity and reusability for selective hydrogenation under mild conditions.

Graphical abstract: The ionic liquid microphase enhances the catalytic activity of Pd nanoparticles supported by a metal–organic framework

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Supplementary files

Article information


Submitted
15 Jun 2015
Accepted
08 Jul 2015
First published
08 Jul 2015

Green Chem., 2015,17, 4178-4182
Article type
Communication
Author version available

The ionic liquid microphase enhances the catalytic activity of Pd nanoparticles supported by a metal–organic framework

L. Peng, J. Zhang, S. Yang, B. Han, X. Sang, C. Liu and G. Yang, Green Chem., 2015, 17, 4178
DOI: 10.1039/C5GC01333J

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