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Issue 6, 2015
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Catalytic allylic arylation of cinnamyl carbonates over palladium nanoparticles supported on a thermoresponsive polymer in water

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Abstract

Poly(NIPAM-co-4-VP) undergoes a phase transition at the low critical solution temperature with a change from the hydrophilic to the hydrophobic core in a hydrophilic solvent. Palladium nanoparticles supported on such a thermoresponsive polymer support were demonstrated to catalyze the Tsuji–Trost reaction for the arylation of various cinnamyl carbonates by arylboronic acids. Therefore, a protocol developed using mild reaction conditions demonstrates the recyclability of the catalyst in an eco-friendly solvent such as water.

Graphical abstract: Catalytic allylic arylation of cinnamyl carbonates over palladium nanoparticles supported on a thermoresponsive polymer in water

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Supplementary files

Article information


Submitted
07 Apr 2015
Accepted
02 May 2015
First published
05 May 2015

Green Chem., 2015,17, 3579-3583
Article type
Paper
Author version available

Catalytic allylic arylation of cinnamyl carbonates over palladium nanoparticles supported on a thermoresponsive polymer in water

Y. Lee, S. Shabbir, S. Lee, H. Ahn and H. Rhee, Green Chem., 2015, 17, 3579
DOI: 10.1039/C5GC00745C

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