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Issue 5, 2015
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Broadening the chemical scope of laccases: selective deprotection of N-benzyl groups

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Abstract

Laccase from Trametes versicolor together with TEMPO has been found to be a very efficient system to deprotect N-benzylated primary amines, differing from previously described methods since it uses oxygen as a mild oxidant in aqueous medium. Chemoselective removal of the benzyl group was achieved with excellent yields when secondary amines and alcohol moieties were also present.

Graphical abstract: Broadening the chemical scope of laccases: selective deprotection of N-benzyl groups

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Publication details

The article was received on 09 Mar 2015, accepted on 30 Mar 2015 and first published on 30 Mar 2015


Article type: Communication
DOI: 10.1039/C5GC00525F
Citation: Green Chem., 2015,17, 2794-2798

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    Broadening the chemical scope of laccases: selective deprotection of N-benzyl groups

    L. Martínez-Montero, A. Díaz-Rodríguez, V. Gotor, V. Gotor-Fernández and I. Lavandera, Green Chem., 2015, 17, 2794
    DOI: 10.1039/C5GC00525F

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