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Issue 5, 2015

Synthesis of dendrimer-supported ferrocenylmethyl aziridino alcohol ligands and their application in asymmetric catalysis

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Abstract

A series of N-ferrocenylmethyl aziridino alcohol ligands bearing Fréchet-type dendrimers were synthesized and applied in the asymmetric addition of diethylzinc to aldehydes affording chiral alcohols in excellent yields (up to 99%) and excellent enantioselectivities (ee, up to 98%). The ligands could be recycled and reused eight times for such a reaction with almost the original high reactivity and selectivity.

Graphical abstract: Synthesis of dendrimer-supported ferrocenylmethyl aziridino alcohol ligands and their application in asymmetric catalysis

Supplementary files

Article information


Submitted
16 Dec 2014
Accepted
26 Feb 2015
First published
02 Mar 2015

Green Chem., 2015,17, 2924-2930
Article type
Paper
Author version available

Synthesis of dendrimer-supported ferrocenylmethyl aziridino alcohol ligands and their application in asymmetric catalysis

W. Zhao, N. Liu, G. Li, D. Chen, A. Zhang, M. Wang and L. Liu, Green Chem., 2015, 17, 2924 DOI: 10.1039/C4GC02447H

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