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Issue 5, 2015
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Synthesis of dendrimer-supported ferrocenylmethyl aziridino alcohol ligands and their application in asymmetric catalysis

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Abstract

A series of N-ferrocenylmethyl aziridino alcohol ligands bearing Fréchet-type dendrimers were synthesized and applied in the asymmetric addition of diethylzinc to aldehydes affording chiral alcohols in excellent yields (up to 99%) and excellent enantioselectivities (ee, up to 98%). The ligands could be recycled and reused eight times for such a reaction with almost the original high reactivity and selectivity.

Graphical abstract: Synthesis of dendrimer-supported ferrocenylmethyl aziridino alcohol ligands and their application in asymmetric catalysis

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Publication details

The article was received on 16 Dec 2014, accepted on 26 Feb 2015 and first published on 02 Mar 2015


Article type: Paper
DOI: 10.1039/C4GC02447H
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Citation: Green Chem., 2015,17, 2924-2930

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    Synthesis of dendrimer-supported ferrocenylmethyl aziridino alcohol ligands and their application in asymmetric catalysis

    W. Zhao, N. Liu, G. Li, D. Chen, A. Zhang, M. Wang and L. Liu, Green Chem., 2015, 17, 2924
    DOI: 10.1039/C4GC02447H

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