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Issue 11, 2013
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Nitroxide-catalyzed transition-metal-free aerobic oxidation processes

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Abstract

Advances in the field of transition-metal-free nitroxide-catalyzed aerobic oxidation processes are covered in this critical review. Along with the relevant physical properties of nitroxides, their application as oxidation catalysts by using dioxygen as a reagent or terminal oxidant will be discussed. The second part of the review focuses on the use of TEMPO-based nitroxides as catalysts for aerobic alcohol oxidation. Mechanistic studies will also be addressed (130 references).

Graphical abstract: Nitroxide-catalyzed transition-metal-free aerobic oxidation processes

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Article information


Submitted
23 Jul 2013
Accepted
20 Aug 2013
First published
20 Aug 2013

Green Chem., 2013,15, 3116-3134
Article type
Critical Review

Nitroxide-catalyzed transition-metal-free aerobic oxidation processes

S. Wertz and A. Studer, Green Chem., 2013, 15, 3116
DOI: 10.1039/C3GC41459K

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