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Issue 10, 2012
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Recycling of allylic alkylation Pd catalysts containing phosphine-imidazoline ligands in ionic liquids

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Abstract

An efficient catalytic system to perform allylic alkylation in ionic liquids based on a Pd/phosphine imidazoline system has been designed. This system affords very good results (ee's up to 95%) when used with the appropriate ionic liquid as well as under microwave conditions. Recycling experiments were conducted showing very promising results.

Graphical abstract: Recycling of allylic alkylation Pd catalysts containing phosphine-imidazoline ligands in ionic liquids

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Publication details

The article was received on 13 May 2012, accepted on 15 Aug 2012 and first published on 16 Aug 2012


Article type: Communication
DOI: 10.1039/C2GC35732A
Green Chem., 2012,14, 2715-2718

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    Recycling of allylic alkylation Pd catalysts containing phosphine-imidazoline ligands in ionic liquids

    V. de la Fuente, N. Fleury-Brégeot, S. Castillón and C. Claver, Green Chem., 2012, 14, 2715
    DOI: 10.1039/C2GC35732A

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