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Issue 4, 2012
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Photooxygenations in a bubble column reactor

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Abstract

A novel column reactor was constructed and successfully applied to dye-sensitized photooxygenation reactions in aqueous alcohol solutions. The air flow pattern within the narrow glass column could be controlled via the size of the air inlet capillary. Using a 500 μm capillary, a slug flow pattern was realized which allowed for superior mass transfer and light transparency within a thin solvent layer. These features subsequently gave higher conversion rates and isolated yields.

Graphical abstract: Photooxygenations in a bubble column reactor

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Publication details

The article was received on 11 Nov 2011, accepted on 10 Jan 2012 and first published on 01 Feb 2012


Article type: Communication
DOI: 10.1039/C2GC16439F
Green Chem., 2012,14, 888-892

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    Photooxygenations in a bubble column reactor

    A. Yavorskyy, O. Shvydkiv, C. Limburg, K. Nolan, Y. M. C. Delauré and M. Oelgemöller, Green Chem., 2012, 14, 888
    DOI: 10.1039/C2GC16439F

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