Issue 11, 2011
From the journal:

Green Chemistry

Heterogeneously catalysed Strecker-type reactions using supported Co(ii) catalysts: microwave vs. conventional heating†

Fatemeh Rajabi,*a   Saghar Nourian,b   Sara Ghiassian,b   Alina M. Balu,c   Mohammad Reza Saidi,*b   Juan Carlos Serrano-Ruizc  and  Rafael Luquec  

* Corresponding authors

a Department of Science, Payame Noor Univesity, P. O. Box: 19395-4697, Tehran, Iran
E-mail: f_rajabi@pnu.ac.ir
Fax: +98 2813344081
Tel: +98 2813336366

b Department of Chemistry, Sharif University of Technology, P. O. Box 11465-9516, Tehran, Iran
E-mail: saidi@sharif.edu
Fax: +98 21 6601 2983
Tel: +98 21 6600 5718

c Departamento de Química Orgánica, Universidad de Cordoba, Campus de Rabanales, Edificio Marie Curie (C-3), Ctra Nnal IV-A, Km 396, Cordoba, Spain
E-mail: q62alsor@uco.es

Abstract

A range of α-aminonitriles could be efficiently prepared from various aldehydes/ketones and primary or secondary amines using a highly active and stable Co(II) complex supported on different mesoporous supports at both room temperature and low temperature microwave irradiation under solventless conditions. Catalysts were also highly reusable under the investigated reaction conditions and could be reused at least 10 times without loss of catalytic activity.

Graphical abstract: Heterogeneously catalysed Strecker-type reactions using supported Co(ii) catalysts: microwave vs. conventional heating

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Article information

DOI
https://doi.org/10.1039/C1GC15741H
Article type
Paper
Submitted
23 Jun 2011
Accepted
15 Aug 2011
First published
09 Sep 2011

Green Chem., 2011,13, 3282-3289

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Heterogeneously catalysed Strecker-type reactions using supported Co(II) catalysts: microwave vs. conventional heating

F. Rajabi, S. Nourian, S. Ghiassian, A. M. Balu, M. R. Saidi, J. C. Serrano-Ruiz and R. Luque, Green Chem., 2011, 13, 3282 DOI: 10.1039/C1GC15741H

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