Issue 9, 2011
From the journal:

Green Chemistry

Rapid and selective deallylation of allyl ethers and esters using iodine in polyethylene glycol-400†

Shankaraiah G. Konda,a   Vivek T. Humnea  and  Pradeep D. Lokhandea  

a Organic Research Laboratory, Department of Chemistry, University of Pune, Pune, India
E-mail: kondasg@rediffmail.com
Fax: +9120 25691728
Tel: +9120 25896199

Abstract

A simple and selective deallylation of allyl ethers and esters using iodine (10 mol%) in polyethylene glycol-400 as a green reaction solvent is described. The reaction was performed at room temperature with various aryl/alkyl allyl ethers and esters in good to excellent yields. The present methodology includes inexpensive catalyst, easy work-up, benign reaction conditions and high selectivity.

Graphical abstract: Rapid and selective deallylation of allyl ethers and esters using iodine in polyethylene glycol-400

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Article information

DOI
https://doi.org/10.1039/C1GC15153C
Article type
Communication
Submitted
09 Feb 2011
Accepted
15 Jun 2011
First published
18 Jul 2011

Green Chem., 2011,13, 2354-2358

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Rapid and selective deallylation of allyl ethers and esters using iodine in polyethylene glycol-400

S. G. Konda, V. T. Humne and P. D. Lokhande, Green Chem., 2011, 13, 2354 DOI: 10.1039/C1GC15153C

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