Issue 6, 2010
From the journal:

Green Chemistry

Efficient copper-catalyzed N-arylations of nitrogen-containing heterocycles and aliphatic amines in water†

Xufeng Li,ab   Daoshan Yang,a   Yuyang Jiangb  and  Hua Fu*a  

* Corresponding authors

a Key Laboratory of Bioorganic Phosphorus Chemistry and Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing, P. R. China
E-mail: fuhua@mail.tsinghua.edu.cn

b Key Laboratory of Chemical Biology (Guangdong Province), Graduate School of Shenzhen, Tsinghua University, Shenzhen, P. R. China

Abstract

A simple and efficient copper-catalyzed method has been developed for N-arylations of nitrogen-containing heterocycles and aliphatic amines in water. The protocol uses (1E,2E)-oxalaldehyde dioxime (OADO) as the ligand, and water as the solvent, and shows good tolerance towards various functional groups.

Graphical abstract: Efficient copper-catalyzed N-arylations of nitrogen-containing heterocycles and aliphatic amines in water

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Article information

DOI
https://doi.org/10.1039/C002172E
Article type
Paper
Submitted
03 Feb 2010
Accepted
19 Mar 2010
First published
05 May 2010

Green Chem., 2010,12, 1097-1105

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Efficient copper-catalyzed N-arylations of nitrogen-containing heterocycles and aliphatic amines in water

X. Li, D. Yang, Y. Jiang and H. Fu, Green Chem., 2010, 12, 1097 DOI: 10.1039/C002172E

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