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Issue 3, 2010
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An improved high yielding immobilization of vanadium Schiff base complexes on mesoporous silicavia azide–alkynecycloaddition for the oxidation of sulfides

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Abstract

Azide–alkyne [3+2] cycloadditionclick reaction” was found to be a simple yet improved approach for the efficient immobilization of oxo–vanadium(IV) tridentate Schiff base complexes to mesoporous silica via covalent attachment as it occurred under mild reaction conditions and provided high catalyst loading compared to the direct immobilization of oxo–vanadium(IV) tridentate Schiff base complex to 3-chloropropylsilyl functionalized silica support.

Graphical abstract: An improved high yielding immobilization of vanadium Schiff base complexes on mesoporous silica via azide–alkyne cycloaddition for the oxidation of sulfides

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Submitted
22 Aug 2009
Accepted
03 Dec 2009
First published
07 Jan 2010

Green Chem., 2010,12, 374-377
Article type
Communication

An improved high yielding immobilization of vanadium Schiff base complexes on mesoporous silica via azide–alkyne cycloaddition for the oxidation of sulfides

S. L. Jain, B. S. Rana, B. Singh, A. K. Sinha, A. Bhaumik, M. Nandi and B. Sain, Green Chem., 2010, 12, 374
DOI: 10.1039/B917382J

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