Issue 7, 2009

Hydrosilylation of functionalised olefins catalysed by rhodium siloxide complexes in ionic liquids

Abstract

The use of ionic liquids for the immobilization of rhodium siloxide complexes has permitted development of highly effective catalysts for the hydrosilylation processes. Herein, we report the synthesis of organosilicon compounds in a biphasic reaction setup, allowing separation of the product, recovery and reuse of the catalyst, which is fundamental from the point of view of “green chemistry”.

Graphical abstract: Hydrosilylation of functionalised olefins catalysed by rhodium siloxide complexes in ionic liquids

Article information

Article type
Paper
Submitted
03 Nov 2008
Accepted
09 Apr 2009
First published
29 Apr 2009

Green Chem., 2009,11, 1045-1051

Hydrosilylation of functionalised olefins catalysed by rhodium siloxide complexes in ionic liquids

H. Maciejewski, K. Szubert, B. Marciniec and J. Pernak, Green Chem., 2009, 11, 1045 DOI: 10.1039/B819310J

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