Issue 6, 2008
From the journal:

Green Chemistry

Transfer hydrogenation of aldehydes on amphiphilic catalyst assembled at the interface of emulsion droplets†

Jun Li,a   Yanmei Zhang,a   Difei Han,a   Guoqing Jia,a   Jinbo Gao,a   Lin Zhonga  and  Can Li*a  

* Corresponding authors

a State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian, China
E-mail: canli@dicp.ac.cn
Web: http://www.canli.dicp.ac.cn/
Fax: 86-411-84694447
Tel: 86-411-84379070

Abstract

An amphiphilic polymer-based iridium catalyst assembled at the interface of emulsion droplets shows a remarkable rate acceleration for the transfer hydrogenation of aldehydes in water, which may result from the high surface area of the emulsion droplets and the high local concentrations of reactants around the active sites.

Graphical abstract: Transfer hydrogenation of aldehydes on amphiphilic catalyst assembled at the interface of emulsion droplets

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Article information

DOI
https://doi.org/10.1039/B803209B
Article type
Communication
Submitted
25 Feb 2008
Accepted
15 Apr 2008
First published
24 Apr 2008

Green Chem., 2008,10, 608-611

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Transfer hydrogenation of aldehydes on amphiphilic catalyst assembled at the interface of emulsion droplets

J. Li, Y. Zhang, D. Han, G. Jia, J. Gao, L. Zhong and C. Li, Green Chem., 2008, 10, 608 DOI: 10.1039/B803209B

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