The Pt(II)-catalyzed Baeyer–Villiger oxidation of cyclohexanone with H2O2 in ionic liquids

Valeria Conte; Barbara Floris; Pierluca Galloni; Valentina Mirruzzo; Alessandro Scarso; Daniela Sordi; Giorgio Strukul

doi:10.1039/B416923A

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The Pt(ii)-catalyzed Baeyer–Villiger oxidation of cyclohexanone with H₂O₂ in ionic liquids†

Valeria Conte,*^a Barbara Floris,^a Pierluca Galloni,^a Valentina Mirruzzo,^a Alessandro Scarso,^b Daniela Sordi^a and Giorgio Strukul^b

Author affiliations

* Corresponding authors

^a Dipartimento di Scienze e Tecnologie Chimiche, Università di Roma “Tor Vergata”, via della Ricerca Scientifica, 00133, Roma, Italy
E-mail: valeria.conte@uniroma2.it
Fax: +39 06 72594 328
Tel: +39 06 72594 014

^b Dipartimento di Chimica, Università di Venezia, Dorsoduro 2137, 30123 Venezia, Italy
E-mail: strukul@unive.it
Fax: +39 041 2348517
Tel: +39 041 2348931

Abstract

The Pt(II)-catalyzed Baeyer–Villiger oxidation of cyclohexanone with H₂O₂ in a two-phase system, H₂O–IL, is a viable procedure, characterized by synthetically interesting yields, better than those of the same reaction in H₂O–halogenated solvents.

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Article information

DOI: https://doi.org/10.1039/B416923A
Article type: Communication
Submitted: 09 Nov 2004
Accepted: 03 Feb 2005
First published: 14 Feb 2005

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Green Chem., 2005,7, 262-266

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The Pt(II)-catalyzed Baeyer–Villiger oxidation of cyclohexanone with H₂O₂ in ionic liquids

V. Conte, B. Floris, P. Galloni, V. Mirruzzo, A. Scarso, D. Sordi and G. Strukul, Green Chem., 2005, 7, 262 DOI: 10.1039/B416923A

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