Issue 2, 2003

A green protocol for the silylation of alcohols using bonded fluorous phase catalysis

Abstract

The surface of a solid silica support has been functionalized with long perfluoroalkyl chains. The resulting surface layer readily adsorbs fluorous molecules from organic solutions. In this way, dirhodium(II) perfluorocarboxylate catalysts can be conveniently immobilized on a solid support. The resulting Bonded Fluorous Phase (BFP) catalysts display a high activity in the silane alcoholysis reaction using a solventless procedure and are easily recycled.

Graphical abstract: A green protocol for the silylation of alcohols using bonded fluorous phase catalysis

Article information

Article type
Paper
Submitted
07 Nov 2002
First published
27 Jan 2003

Green Chem., 2003,5, 170-173

A green protocol for the silylation of alcohols using bonded fluorous phase catalysis

A. Biffis, M. Zecca and M. Basato, Green Chem., 2003, 5, 170 DOI: 10.1039/B210992A

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