Issue 6, 2000

The preparation and use of novel immobilised guanidine catalysts in base-catalysed epoxidation and condensation reactions

Abstract

Novel guanidine bases supported on silicas and Micelle Templated Silicas (MTS) have been prepared, and investigated in the base catalysed epoxidation of electron deficient alkenes with excellent conversions and selectivities both with respect to the alkene and the primary oxidant. They are also efficient catalysts for the condensation of malonic acid with heptanal.

Article information

Article type
Paper
Submitted
21 Jul 2000
First published
09 Nov 2000

Green Chem., 2000,2, 283-288

The preparation and use of novel immobilised guanidine catalysts in base-catalysed epoxidation and condensation reactions

A. C. Blanc, D. J. Macquarrie, S. Valle, G. Renard, C. R. Quinn and D. Brunel, Green Chem., 2000, 2, 283 DOI: 10.1039/B005929N

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