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Issue 4, 1997
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Some aspects of the NO reduction reaction over rhodium catalysts

Abstract

A theoretical study has been performed of the reduction of NO by CO over Rh catalysts solving the system of equations generated by applying a steady state to the adsorbed species to determine the influence of the rates of the NO dissociation and δ-N 2 production steps on the catalyst activity (measured as CO 2 production) and selectivity to N 2 O. As a general observation, it is concluded that joint data on activity and selectivity are required to make a critical selection of the kinetic parameters that can interpret adequately the experimental data.

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Article information


J. Chem. Soc., Faraday Trans., 1997,93, 639-642
Article type
Paper

Some aspects of the NO reduction reaction over rhodium catalysts

P. Araya and J. Corte′s, J. Chem. Soc., Faraday Trans., 1997, 93, 639
DOI: 10.1039/A605441B

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