Issue 19, 1995

Reaction of H+ with tetraphenylborates : an example of an EC mechanism at liquid/liquid interfaces

Abstract

The reaction of H+ electrochemically transferred from an aqueous to an organic immiscible phase, with tetraphenylborate and tetrakis(4-chlorophenyl)borate has been studied by cyclic voltammetry and potential-step measurements. The theory of these EC reactions is presented, and it is shown that the rate constant of the chemical step following charge transfer can be easily estimated from the sweep-rate dependence of the voltammograms, by analysing the conditions for which a minimum in the reverse sweep is not observed.

Article information

Article type
Paper

J. Chem. Soc., Faraday Trans., 1995,91, 3433-3439

Reaction of H+ with tetraphenylborates : an example of an EC mechanism at liquid/liquid interfaces

A. Kontturi, K. Kontturi, L. Murtomäki and D. J. Schiffrin, J. Chem. Soc., Faraday Trans., 1995, 91, 3433 DOI: 10.1039/FT9959103433

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements