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Volume 177, 2015
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Probing electronic and vibrational dynamics in molecules by time-resolved photoelectron, Auger-electron, and X-ray photon scattering spectroscopy

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Abstract

We present a unified description for time-resolved electron and photon scattering spectroscopies from molecules prepared in nonstationary states. Signals are expressed in terms of superoperator Green's functions and a systematic procedure for treating various degrees of freedom consistently at different levels of theory is developed. The standard Fermi Golden Rule expressions for photoelectron spectra, which are limited to broad, slowly-varying signals, are obtained as a limiting case of our more general theory that applies to broader parameter regimes.

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Publication details

The article was received on 17 Sep 2014, accepted on 04 Nov 2014 and first published on 02 Mar 2015


Article type: Paper
DOI: 10.1039/C4FD00178H
Faraday Discuss., 2015,177, 405-428

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    Probing electronic and vibrational dynamics in molecules by time-resolved photoelectron, Auger-electron, and X-ray photon scattering spectroscopy

    K. Bennett, M. Kowalewski and S. Mukamel, Faraday Discuss., 2015, 177, 405
    DOI: 10.1039/C4FD00178H

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