Issue 9, 1983

NO fluorescence during vacuum-ultraviolet photodissociation of CFCl2NO

Abstract

Gas-phase photodissociation of CFCl2NO at 147 nm results in the formation of electronically excited NO in the B2Π state, giving rise to the well known NO β-emission bands. Collisional effects consequent upon the addition of helium lead to the appearance of fluorescence from the NO(A2+) state with emission from the ν′= 2 and 3 levels dominating the spectrum. The results are compared with data obtained previously for other nitrosocompounds.

Article information

Article type
Paper

J. Chem. Soc., Faraday Trans. 2, 1983,79, 1355-1363

NO fluorescence during vacuum-ultraviolet photodissociation of CFCl2NO

C. A. F. Johnson, J. Chem. Soc., Faraday Trans. 2, 1983, 79, 1355 DOI: 10.1039/F29837901355

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