SCHEDULED MAINTENANCE
Equimolar mixtures of divalent transition-metal perchlorates in N,N-dimethylformamide (DMF) have been used as constant ionic media for studying the formation of monochloride complexes of metal cations. The derived stability constants of the MCl(DMF)+5-type complexes (M = Mn, Co, Ni, Cu) disobey the Irving–Williams series forming the sequence Mn > Co > Ni < Cu.
W. Grzybkowski and M. Pilarczyk, J. Chem. Soc., Faraday Trans. 1, 1986, 82, 1745 DOI: 10.1039/F19868201745
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