Issue 1, 2012

Characteristics of surface ozone at an urban site of Xi'an in Northwest China

Abstract

Surface ozone concentrations in Xi'an, China were monitored from March 23, 2008 to January 12, 2009 using the Model ML/EC9810 ozone analyzer. The daily average O3 ranged from <1 ppb to 64.2 ppbv with an annual average of 16.0 ppbv. The seasonal average of O3 in summer (32.5 ppbv) was more than 10 times higher than that in winter (3.0 ppbv). A significant positive correlation was found between ozone concentration and ambient temperature, indicating that the intensity of solar radiation was one of the several major factors controlling surface ozone production. Using the NOAA HYSPLIT 4 trajectory model, the three longest O3 pollution episodes were found to be associated with the high biogenic volatile organic carbon (BVOC) emissions from the vegetation of Qinling Mountains. No significant weekday and weekend difference in O3 levels was detected due to the non-significant change in NOx emissions. O3 depletion by NO emission directly emitted from vehicles, low oxygenated VOC concentrations, and low-level solar radiation caused by high aerosol loading all contributed to the low levels of O3 found in Xi'an compared to other cities and rural areas.

Graphical abstract: Characteristics of surface ozone at an urban site of Xi'an in Northwest China

Article information

Article type
Paper
Submitted
06 Jul 2011
Accepted
28 Sep 2011
First published
09 Nov 2011

J. Environ. Monit., 2012,14, 116-126

Characteristics of surface ozone at an urban site of Xi'an in Northwest China

X. Wang, Z. Shen, J. Cao, L. Zhang, L. Liu, J. Li, S. Liu and Y. Sun, J. Environ. Monit., 2012, 14, 116 DOI: 10.1039/C1EM10541H

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