Occurrence and fate of pharmaceuticals and personal care products in drinkingwater in southern China

Abstract

Occurrence and fate of pharmaceuticals and personal care products (PPCPs) in drinking water was investigated in southern China. Fifteen and twelve PPCPs were detected with concentrations of 0–36 ng L⁻¹ in source water and of 0–20 ng L⁻¹ in treated water, respectively. Four PPCPs were detected with concentrations of approximately 1 ng L⁻¹ in drinking water of distribution network. Conventional water treatment processes removed the types and average concentrations of PPCPs by 30% and above 50%, respectively. Advanced water treatment processes were more efficient in the removal of most PPCPs, with the types and concentrations reduced by 50% and approximately 90%, respectively. Molecular properties of PPCPs had an important influence on their behaviors during water treatment. pK_a (acidity coefficient) and K_oc (organic carbon partition coefficient) of PPCPs appeared to have a combined effect on PPCPs removal during coagulation and oxidation. Adsorption and biodegradation were two possible mechanisms responsible for PPCPs removal during sand filtration.