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Issue 5, 2014
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Enabling ammonia-borane: co-oligomerizaiton of ammonia-borane and amine-boranes yield liquid products

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Abstract

In contrast to neat ammonia-borane (AB), the thermal decomposition of AB with N-substituted amine-boranes yields a liquid product after extended heating and H2 release. NMR and GPC data indicate that co-oligomerization has occurred. These results show promise for developing high energy density AB-based fuel formulations for automotive applications.

Graphical abstract: Enabling ammonia-borane: co-oligomerizaiton of ammonia-borane and amine-boranes yield liquid products

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The article was received on 07 Feb 2014, accepted on 20 Mar 2014 and first published on 21 Mar 2014


Article type: Communication
DOI: 10.1039/C4EE00442F
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Citation: Energy Environ. Sci., 2014,7, 1653-1656

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    Enabling ammonia-borane: co-oligomerizaiton of ammonia-borane and amine-boranes yield liquid products

    A. E. Carre-Burritt, B. L. Davis, B. D. Rekken, N. Mack and T. A. Semelsberger, Energy Environ. Sci., 2014, 7, 1653
    DOI: 10.1039/C4EE00442F

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