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Issue 1, 2014
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Upgrading of lignin-derived bio-oils by catalytic hydrodeoxygenation

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The incentive for use of renewable resources to replace fossil sources is motivating extensive research on new and alternative fuels derived from biomass. Bio-oils derived from cellulosic biomass offer the prospect of becoming a major feedstock for production of fuels and chemicals, and lignin is a plentiful, underutilized component of cellulosic biomass. Lignin conversion requires depolymerization and removal of oxygen. Likely processes for lignin conversion involve depolymerization (e.g., by pyrolysis) and catalytic upgrading of the resultant bio-oils. A major goal of the upgrading is catalytic hydrodeoxygenation (HDO), which involves reactions with hydrogen that produce hydrocarbons and water. The aim of this review is to present a critical introduction to HDO chemistry focused on compounds derived from lignin, including a summary of HDO reactions and those that accompany them, with a comparison of catalysts addressing their activities, selectivities, and stabilities. The reactions are evaluated in terms of reaction pathways of compounds representative of lignin-derived bio-oils, including anisole, guaiacol, and phenol. The review includes recommendations for further research and an attempt to place HDO in a context of options for renewable fuels and chemicals, but it does not provide an economic assessment.

Graphical abstract: Upgrading of lignin-derived bio-oils by catalytic hydrodeoxygenation

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Publication details

The article was received on 13 Sep 2013, accepted on 08 Nov 2013 and first published on 11 Nov 2013

Article type: Review Article
DOI: 10.1039/C3EE43081B
Energy Environ. Sci., 2014,7, 103-129

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    Upgrading of lignin-derived bio-oils by catalytic hydrodeoxygenation

    M. Saidi, F. Samimi, D. Karimipourfard, T. Nimmanwudipong, B. C. Gates and M. R. Rahimpour, Energy Environ. Sci., 2014, 7, 103
    DOI: 10.1039/C3EE43081B

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