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Issue 6, 2011
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Implications of remote water molecules on the electron transfer coupled processes at a nonporphyrinic Mn(iii)-hydroxido complex

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Abstract

Electrochemical studies of a new Mn(III)(OH) complex clearly evidence that the presence of outer spheres water molecules is essential for the reversibility of MnIII/II and MnIV/IIIredox processes. In the MnIII/II case we found an isotope effect for D2O and 18OH2 allowing us to propose a mechanism for H2O/HO ligand exchange coupled electron transfer activation of Mn–OH2

Graphical abstract: Implications of remote water molecules on the electron transfer coupled processes at a nonporphyrinic Mn(iii)-hydroxido complex

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Article information


Submitted
21 Jan 2011
Accepted
31 Mar 2011
First published
19 Apr 2011

Energy Environ. Sci., 2011,4, 2041-2044
Article type
Communication

Implications of remote water molecules on the electron transfer coupled processes at a nonporphyrinic Mn(III)-hydroxido complex

S. El Ghachtouli, B. Lassalle-Kaiser, P. Dorlet, R. Guillot, E. Anxolabéhère-Mallart, C. Costentin and A. Aukauloo, Energy Environ. Sci., 2011, 4, 2041
DOI: 10.1039/C1EE01078F

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