Ti2Ni alloy: a potential candidate for hydrogenstorage in nickel/metal hydride secondary batteries

Abstract

An amorphous Ti₂Ni alloy, prepared by mechanical milling of a crystalline Ti₂Ni alloy, was heat-treated at several temperatures. The crystalline behavior of the amorphous alloy was studied , relative to a multi-stage crystallization mode, using X-ray diffraction, differential scanning calorimetry, and electron diffraction. X-Ray photoelectron spectroscopy was performed to analyze the surface structure of the alloys. The alloy that was heat-treated at 693 K, with a non-equilibrium bulk structure and a protective surface layer, has a high discharge capacity and good cycling stability. The issue of severe capacity loss of Ti₂Ni-based alloys, which has caused problems for many years, has been significantly improved.