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Issue 40, 2020
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Amidinate based indium(iii) monohalides and β-diketiminate stabilized In(ii)–In(ii) bond: synthesis, crystal structure, and computational study

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Abstract

Synthesis and bonding aspects of mononuclear bis-amidinate indium(III) monohalides L2InX (1–3), where L = PhC(NtBu)2; X is F (1), Br (2) or I (3) and β-diketiminate (NacNac) stabilized In(II) dimer (MesNacNac)2In2Br2 (4) with In–In bond are reported along with the single-crystal X-ray structures of 2–4.

Graphical abstract: Amidinate based indium(iii) monohalides and β-diketiminate stabilized In(ii)–In(ii) bond: synthesis, crystal structure, and computational study

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Article information


Submitted
09 Sep 2020
Accepted
30 Sep 2020
First published
01 Oct 2020

This article is Open Access

Dalton Trans., 2020,49, 14231-14236
Article type
Paper

Amidinate based indium(III) monohalides and β-diketiminate stabilized In(II)–In(II) bond: synthesis, crystal structure, and computational study

S. Banerjee, S. Dutta, S. K. Sarkar, N. Graw, R. Herbst-Irmer, D. Koley, D. Stalke and H. W. Roesky, Dalton Trans., 2020, 49, 14231
DOI: 10.1039/D0DT03161E

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