Conducting neutral gold bisdithiolene complex [Au(dspdt)2]˙

Mariana F. G. Velho; Rafaela A. L. Silva; Graça Brotas; Elsa B. Lopes; Isabel C. Santos; Ana Charas; Dulce Belo; Manuel Almeida

doi:10.1039/D0DT02931A

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Conducting neutral gold bisdithiolene complex [Au(dspdt)₂]˙†

Mariana F. G. Velho,^ab Rafaela A. L. Silva,^a Graça Brotas,^a Elsa B. Lopes,

^ac Isabel C. Santos,

^ac Ana Charas,^b Dulce Belo

*^ac and Manuel Almeida

*^ac

Author affiliations

* Corresponding authors

^a Centro de Ciências e Tecnologias Nucleares, Instituto Superior Técnico, Universidade de Lisboa, E.N. 10, P-2695-066 Bobadela LRS, Portugal
E-mail: dbelo@ctn.tecnico.ulisboa.pt, malmeida@ctn.tecnico.ulisboa.pt

^b Instituto de Telecomunicações, Instituto Superior Técnico, Av. Rovisco Pais 1, Lisboa, Portugal

^c Departamento de Engenharia e Ciências Nucleares, Instituto Superior Técnico, Universidade de Lisboa, E.N. 10, P-2695-066 Bobadela LRS, Portugal

Abstract

[Au(dspdt)₂] (dspdt = 2,3-dihydro-5,6-selenophenedithiolate) is an unprecedented example of a neutral gold bisdithiolene complex with a unique structure composed of interacting dimer and trimer chains displaying relatively high electrical conductivity (0.1 S cm⁻¹ at room temperature).

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Article information

DOI: https://doi.org/10.1039/D0DT02931A
Article type: Paper
Submitted: 20 Aug 2020
Accepted: 21 Sep 2020
First published: 23 Sep 2020

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Dalton Trans., 2020,49, 13737-13743

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Conducting neutral gold bisdithiolene complex [Au(dspdt)₂]˙

M. F. G. Velho, R. A. L. Silva, G. Brotas, E. B. Lopes, I. C. Santos, A. Charas, D. Belo and M. Almeida, Dalton Trans., 2020, 49, 13737 DOI: 10.1039/D0DT02931A

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