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Issue 45, 2020
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Synthesis of atomically precise single-crystalline Ru2-based coordination polymers

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Abstract

Methods to incorporate kinetically inert metal nodes and highly basic ligands into single-crystalline metal–organic frameworks (MOFs) are scarce, which prevents synthesis and systematic variation of many potential heterogeneous catalyst materials. Here we demonstrate that metallopolymerization of kinetically inert Ru2 metallomonomers via labile Ag–N bonds provides access to a family of atomically precise single-crystalline Ru2-based coordination polymers with varied network topology and primary coordination sphere.

Graphical abstract: Synthesis of atomically precise single-crystalline Ru2-based coordination polymers

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Supplementary files

Article information


Submitted
23 Jun 2020
Accepted
12 Jul 2020
First published
14 Jul 2020

Dalton Trans., 2020,49, 16077-16081
Article type
Communication
Author version available

Synthesis of atomically precise single-crystalline Ru2-based coordination polymers

W. Gao, G. P. Van Trieste III and D. C. Powers, Dalton Trans., 2020, 49, 16077 DOI: 10.1039/D0DT02233K

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