Issue 23, 2020
From the journal:

Dalton Transactions

Accelerating role of deaggregation agents in lithium-catalysed hydrosilylation of carbonyl compounds†

Cristina Ruiz, ORCID logo ‡a   Álvaro Raya-Barón,‡a   Manuel A. Ortuño ORCID logo *b  and  Ignacio Fernández ORCID logo *a  

* Corresponding authors

a Department of Chemistry and Physics, Research centre CIAIMBITAL, Ctra. Sacramento, s/n, 04120 Almería, Spain
E-mail: ifernan@ual.es

b Institute of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology (BIST), Av. Països Catalans 16, 43007 Tarragona, Spain
E-mail: mortuno@iciq.es

Abstract

A combined computational and experimental approach demonstrates the accelerating role of deaggregation agents, especially HMPA, in the Li-catalysed hydrosilylation of acetophenone in THF solution under very mild conditions.

Graphical abstract: Accelerating role of deaggregation agents in lithium-catalysed hydrosilylation of carbonyl compounds

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Article information

DOI
https://doi.org/10.1039/D0DT01540G
Article type
Paper
Submitted
27 Apr 2020
Accepted
26 May 2020
First published
03 Jun 2020

Dalton Trans., 2020,49, 7932-7937

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Accelerating role of deaggregation agents in lithium-catalysed hydrosilylation of carbonyl compounds

C. Ruiz, Á. Raya-Barón, M. A. Ortuño and I. Fernández, Dalton Trans., 2020, 49, 7932 DOI: 10.1039/D0DT01540G

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