Issue 18, 2020
From the journal:

Dalton Transactions

Bulky Schiff-base ligand supported Co(ii) single-ion magnets with zero-field slow magnetic relaxation†

Guo Peng, ORCID logo *a   Yue Chen,a   Bo Li, ORCID logo *b   Yi-Quan Zhang ORCID logo *c  and  Xiao-Ming Rena  

* Corresponding authors

a School of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816, P. R. China
E-mail: guopeng@njtech.edu.cn

b College of Chemistry and Pharmaceutical Engineering, Nanyang Normal University, Nanyang 473061, P. R. China
E-mail: libozzu0107@163.com

c Jiangsu Key Laboratory for NSLSCS, School of Physical Science and Technology, Nanjing Normal University, Nanjing 210023, P. R. China
E-mail: zhangyiquan@njnu.edu.cn

Abstract

Two mononuclear Co(II) complexes with tetrahedral coordination geometry have been constructed from different bulky Schiff-base ligands. Both complexes exhibit slow magnetic relaxation without a static field and their relaxation behaviors can be tuned by ligand substitution. Clear magnetic hysteresis loops were observed for both complexes at 2 K.

Graphical abstract: Bulky Schiff-base ligand supported Co(ii) single-ion magnets with zero-field slow magnetic relaxation

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Article information

DOI
https://doi.org/10.1039/D0DT00790K
Article type
Communication
Submitted
03 Mar 2020
Accepted
15 Apr 2020
First published
15 Apr 2020

Dalton Trans., 2020,49, 5798-5802

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Bulky Schiff-base ligand supported Co(II) single-ion magnets with zero-field slow magnetic relaxation

G. Peng, Y. Chen, B. Li, Y. Zhang and X. Ren, Dalton Trans., 2020, 49, 5798 DOI: 10.1039/D0DT00790K

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