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Issue 30, 2020
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Incorporation of a nitrogen-rich energetic ligand in a {Yb III2} complex exhibiting slow relaxation of the magnetisation under an applied field

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Abstract

Though often used as the precursor in energetic materials research and organic synthesis, 3,6-dihydrazinyl-1,2,4,5-tetrazine (dhtz) has not been previously explored in coordination chemistry. Herein, we present the first crystalline coordination compound with dhtz, [Yb2(dhtz)(fod)6] (fod = 6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionate). This compound exhibits Single-Molecule Magnet behaviour under an applied magnetic field, and mJ states were resolved through luminescence studies.

Graphical abstract: Incorporation of a nitrogen-rich energetic ligand in a {YbIII2} complex exhibiting slow relaxation of the magnetisation under an applied field

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Article information


Submitted
24 Feb 2020
Accepted
28 Apr 2020
First published
28 Apr 2020

Dalton Trans., 2020,49, 10344-10348
Article type
Communication

Incorporation of a nitrogen-rich energetic ligand in a {YbIII2} complex exhibiting slow relaxation of the magnetisation under an applied field

P. Richardson, D. A. Gálico, J. Ovens, F. A. Sigoli and M. Murugesu, Dalton Trans., 2020, 49, 10344 DOI: 10.1039/D0DT00696C

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