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Issue 11, 2020
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Charge-assisted phosph(v)azane anion receptors

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Abstract

Coordination of Cu(I) or Pd(II) to seleno-cyclodiphosph(V)azanes of the type [RNH(Se)P(μ-NtBu)]2 results in positively charged anion receptor units which have increased anion affinity over the neutral seleno-phosph(V)azanes, due to the increase in electrostatic interactions between the receptor and the guest anions. The same effect is produced by replacement of one of the P[double bond, length as m-dash]Se units by a P–Me+ unit.

Graphical abstract: Charge-assisted phosph(v)azane anion receptors

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Article information


Submitted
10 Feb 2020
Accepted
25 Feb 2020
First published
26 Feb 2020

Dalton Trans., 2020,49, 3403-3407
Article type
Communication

Charge-assisted phosph(V)azane anion receptors

A. J. Plajer, S. Lee, A. D. Bond, J. M. Goodman and D. S. Wright, Dalton Trans., 2020, 49, 3403
DOI: 10.1039/D0DT00489H

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