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Issue 44, 2019
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Citrate-gel preparation and ammonia synthesis activity of compounds in the quaternary (Ni,M)2Mo3N (M = Cu or Fe) systems

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Abstract

Single phase solid solutions based on copper and iron substitution into the nickel sites of Ni2Mo3N are produced using a citrate gel approach followed by ammonolysis. These metal nitrides show good ammonia synthesis activity at 500 °C and ambient pressure. The activity fell with copper content and increased with iron content, although these changes appear to be related to the surface areas of the catalysts. The oxide intermediates from the citrate gel process cleanly converted to the metal nitride under the ammonia synthesis gas stream (75% H2, 25% N2) providing more active catalysts than those pre-nitrided by ammonolysis.

Graphical abstract: Citrate-gel preparation and ammonia synthesis activity of compounds in the quaternary (Ni,M)2Mo3N (M = Cu or Fe) systems

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Publication details

The article was received on 13 Sep 2019, accepted on 24 Oct 2019 and first published on 25 Oct 2019


Article type: Paper
DOI: 10.1039/C9DT03673C
Dalton Trans., 2019,48, 16786-16792
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    Citrate-gel preparation and ammonia synthesis activity of compounds in the quaternary (Ni,M)2Mo3N (M = Cu or Fe) systems

    S. Al Sobhi, J. S. J. Hargreaves, A. L. Hector and S. Laassiri, Dalton Trans., 2019, 48, 16786
    DOI: 10.1039/C9DT03673C

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