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Issue 42, 2019
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A single-ion single-electron cerrous magnet

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Abstract

Herein, we present monometallic Ln(III) complexes [L3Ln(NO3)3] [where Ln = Ce (1) and La (2)] assembled from a simple reaction of the respective lanthanide nitrate hydrate and a bulky phosphonic diamide tBuPO(NHiPr)2 ligand (L), where complex 1 behaves as a single-ion single-electron magnet under a small applied magnetic field. The Ce(III) ion occupies a nine-coordinate distorted muffin-like coordination environment. The combination of direct and Raman process dominates the relaxation dynamics in 1 under the applied dc field. The low-temperature measurements performed with oriented crystals on a micro-SQUID setup exhibits strong tunnelling at zero-field, consistent with the theoretical results where strong mixing of the ground state with higher excited mJ levels is detected and also throws additional insights on the relaxation dynamics of 1. Ab initio calculations have been performed to understand the origin of anisotropy and models have been proposed for future directions.

Graphical abstract: A single-ion single-electron cerrous magnet

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Article information


Submitted
25 Jul 2019
Accepted
21 Aug 2019
First published
22 Aug 2019

Dalton Trans., 2019,48, 15928-15935
Article type
Paper

A single-ion single-electron cerrous magnet

S. K. Gupta, S. Shanmugan, T. Rajeshkumar, A. Borah, M. Damjanović, M. Schulze, W. Wernsdorfer, G. Rajaraman and R. Murugavel, Dalton Trans., 2019, 48, 15928
DOI: 10.1039/C9DT03052B

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