Ligand-directed assembly engineering of trapezoidal {Ti5} building blocks stabilized by dimethylglyoxime

Qing-Rong Ding; Gui-Lan Xu; Lei Zhang; Jian Zhang

doi:10.1039/C9DT02032B

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Ligand-directed assembly engineering of trapezoidal {Ti₅} building blocks stabilized by dimethylglyoxime†

Qing-Rong Ding,^a Gui-Lan Xu,^a Lei Zhang

*^a and Jian Zhang

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* Corresponding authors

^a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China
E-mail: LZhang@fjirsm.ac.cn

Abstract

Through ligand-directed assembly of trapezoidal {Ti₅} building blocks stabilized by dimethylglyoxime, eight titanium-oxo molecular clusters with a sandwich or square planar type structures were successfully constructed, including the first success on the combination of porphyrin and titanium-oxo clusters.

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Article information

DOI: https://doi.org/10.1039/C9DT02032B
Article type: Communication
Submitted: 15 May 2019
Accepted: 04 Jun 2019
First published: 04 Jun 2019

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Dalton Trans., 2019,48, 9916-9919

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Ligand-directed assembly engineering of trapezoidal {Ti₅} building blocks stabilized by dimethylglyoxime

Q. Ding, G. Xu, L. Zhang and J. Zhang, Dalton Trans., 2019, 48, 9916 DOI: 10.1039/C9DT02032B

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Dalton Transactions