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Issue 30, 2019
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A new proton-conducting Bi-carboxylate framework

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Abstract

A new robust Bi-carboxylate metal–organic framework (MOF) IEF-2 was hydrothermally prepared, acting as a proton carrier (σ ∼ 1.1 × 10−4 S cm−1). Such proton conductivity is among the highest reported so far for purely 3D carboxylate-based MOFs, being explained by the existence of a 1D hydrogen-bond network, as suggested by structural analysis and theoretical studies.

Graphical abstract: A new proton-conducting Bi-carboxylate framework

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Article information


Submitted
14 May 2019
Accepted
24 Jun 2019
First published
24 Jun 2019

Dalton Trans., 2019,48, 11181-11185
Article type
Communication

A new proton-conducting Bi-carboxylate framework

S. M. F. Vilela, T. Devic, A. Várez, F. Salles and P. Horcajada, Dalton Trans., 2019, 48, 11181
DOI: 10.1039/C9DT02009H

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